CAS

Chemical Name

% Weight

ACGIH*

ACGIH*

OSHA*

OSHA*

OSHA*

OSHA*

OSHA*

7732-18-5

Water

~96

N/A

N/A

N/A

N/A

N/A

N/A

N/A

7647-01-0

Hydrogen chloride

~3

N/A

N/A

N/A

5 ppm Ceiling; 7 mg/m3 Ceiling

N/A

N/A

N/A

1312-81-8

Lanthanum oxide (La2O3)

~1

N/A

N/A

N/A

N/A

N/A

N/A

N/A

Eye contact

Irritating to eyes

Skin contact

Irritating to skin

Inhalation

May cause irritation of respiratory tract

Ingestion

Harmful if swallowed

If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach

General advice

 Show this safety data sheet to the doctor in attendance

Skin contact

Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes

Consult a physician if necessary

Eye contact

Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes

Keep eye wide open while rinsing

If eye irritation persists, consult a specialist

Inhalation

Move to fresh air in case of accidental inhalation of vapours

If breathing is difficult, give oxygen

Consult a physician if necessary

Ingestion

Call a physician or Poison Control Centre immediately

If swallowed, seek medical advice immediately and show this container or label

If conscious, drink plenty of water

Flash point

NA

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapours

Specific methods

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations

Special protective equipment for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear

NFPA (National Fire Protection Association)

Health - 2

Fire Hazard - 0

Reactivity - 0

Under conditions giving incomplete combustion, hazardous gases produced may consist of:

Hydrogen chloride gas.

Personal precautions

Evacuate personnel to safe areas

Keep people away from and upwind of spill/leak

Wear personal protective equipment

Ensure adequate ventilation

Environmental precautions

Prevent further leakage or spillage if safe to do so

Prevent product from entering drains

Methods for cleaning up

Dam up

Neutralize with lime milk or soda and flush with plenty of water

Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container

After cleaning, flush away traces with water

Technical measures/Precautions

Use only in area provided with appropriate exhaust ventilation

Safe handling advice

Wear personal protective equipment

Technical measures/Precautions

Keep in properly labelled containers

Store at room temperature in the original container

Keep containers tightly closed in a dry, cool and well-ventilated place

Incompatible products

organic materials

reducing agents

Personal protective equipment

Hand protection

impervious gloves

Eye protection

tightly fitting safety goggles

Respiratory protection

Ensure adequate ventilation

Skin and body protection

Chemical resistant apron

Lab coat

Hygiene measures

When using, do not eat, drink or smoke

Regular cleaning of equipment, work area and clothing

Stability

Stable under normal conditions

Hazardous polymerisation does not occur

Materials to avoid

organic materials

reducing agents

Hazardous decomposition

Hydrogen chloride gas

CAS

Chemical Name

% Weight

LD50/oral/rat =

LD50/dermal/rat =

7732-18-5

Water

-96

N/A

N/A

7647-01-0

Hydrogen chloride

~3

Inhalation LC50 Rat: 3124 ppm/1H

Inhalation LC50 Rat: 3124 ppm/1 H

1312-81-8

Lanthanum oxide (La2O3)

〜1

Oral LD50 Rat: >9968 mg/kg

Oral LD50 Rat: >9968 mg/kg

Local effects

Skin irritation

May cause skin irritation and/or dermatitis.

Eye irritation

May cause eye irritation with susceptible persons.

Inhalation

May cause irritation of respiratory tract.

Ingestion

Harmful if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach.

Chronic toxicity

Avoid repeated exposure.

CAS

Chemical Name

% Weight

EFAD*

EFFSD*

EMD-Ecotoxicity

7732-18-5

Water

~96

N/A

N/A

N/A

7647-01-0

Hydrogen chloride

〜3

N/A

48 Hr LC50 bluegill: 3.6 mg/L

N/A

1312-81-8

Lanthanum oxide (La2O3)

~1

N/A

N/A

N/A

Waste from residues / unused products

In accordance with local and national regulations

Contaminated packaging

Empty containers should be taken for local recycling, recovery or waste disposal

CAS

Chemical Name

% Weight

CERCLA/SARA*

CPCL*

NJRTK*

TSCA*

7732-18-5

Water

〜96

N/A

N/A

N/A

Present

7647-01-0

Hydrogen chloride

〜3

5000 lb final RQ;

2270 kg final RQ

N/A

sn 1012; sn 2909 (gas only)

T

1312-81-8

Lanthanum oxide

(La2O3)

~1

N/A

N/A

N/A

Present

CAS

Chemical Name

% Weight

AICS - Australia*

ELINCS - EU list of Notified Chemical Substances (ELINCS)

ENCS*

WHMIS*

7732-18-5

Water

-96

Present

N/A

N/A

Uncontrolled product according to WHMIS classification criteria

7647-01-0

Hydrogen chloride

~3

Present

N/A

1-215

A, D1A, E; E (including 0.02 N, 0.05 N, 0.2 N, 0.333 N,0.5 N); D1B, E (including 10%, 28%,

2 N); D1A, E (including 31.45%, 32%)

1312-81-8

Lanthanum oxide

(La2O3)

-1

Present

N/A

1-757

N/A